Photocatalytic Degradation of Textile Dyes Using Ozonation and Magnetic Nickel Ferrite Nanoparticle

Journal: Vol.9, No.3, Summer 2016 - Article 3   Pages :  163 Until 171

Article Code:

N.M. Mahmoodi: Institute for Color Science and Technology - Department of Environmental Research

Article's abstract:

Dye photodegradation using ozone and Nickel ferrite nanoparticle (NFN) as a photocatalyst was studied. The catalyst was synthesized and characterized by FT-IR, SEM and XRD. Textile dyes including Remazol Red RB (RRRB) and Direct Green B (DGB) were degraded as model compounds. Dye degradation was investigated using UV–Vis and ion chromatography (IC) analyses. The effect of catalyst dosage, pH, salt and initial dye concentration on decolorization was studied. Carboxylic acids were detected as intermediates. It can be concluded that Nickel ferrite nanoparticle could be used as an effective catalyst for photocatalytic ozonation of dyes in colored wastewater.

Synthesis; Nickel ferrite nanoparticle; Photocatalytic ozonation; Dye degradation; Operational parameter

1. M. E. Olya, M. Madadi, F. Tadayon, Synthesis, characterization and application of nano-composite silica aerogel- egg shell for dye removal of colored wastewater. Prog. Color Colorant. Coat., 9(2016), 1-16. 2. A. A. El-Zahhar, N. S. Awwad, Removal of malachite green dye from aqueous solutions using organically modified hydroxyapatite. J. Environ. Chem. Eng., 4(2016), 633-638. 3. J. Si, B. K. Cui, Y. Yuan,Y. C. Dai, Biosorption performances of raw and chemically modified biomasses from Perenniporiasubacida for heterocycle dye Neutral Red. Desalin. Water Treat., 57(2016), 8454-8469. 4. S. S. Batool, Z. Imran, S. Hassan, K. Rasool, M. Ahmad, M. A. Rafiq, Enhanced adsorptive removal of toxic dyes using SiO2 nanofibers. Solid State Sci., 55(2016), 13-20 5. J. Shi, T. Wu, K. Teng, W. Wang, M. Shan, Z. Xu, H. Lv, H. Deng. Simultaneous electrospinning and spraying toward branch-like nanofibrous membranes functionalised with carboxylated MWCNTs for dye removal. Mater. Lett., 166(2016), 26-29. 6. I. Altın, M. Sökmen, Z. Bıyıklıoğlu, Sol gel synthesis of cobalt doped TiO2 and its dye sensitization for efficient pollutant removal. Mater. Sci. Semicond. Process., 45(2016), 36-44. 7. F. Han, H. Li, J. Yang, X. Cai, L. Fu. One-pot synthesis of cuprous oxide-reduced graphene oxide nanocomposite with enhanced photocatalytic and electrocatalytic performance. Physica E, 77(2016),122-126. 8. Y. Zheng, L. Fu, F. Han, A. Wang, W. Cai, J. Yu, J. Yang, F. Peng. Green biosynthesis and characterization of zinc oxide nanoparticles using Corymbiacitriodora leaf extract and their photocatalytic activity. Green Chem. Let. Rev., 8(2015), 59-63. 9. L. Fu, T. Xia, Y. Zheng, J. Yang, A. Wang, Z. Wang. Preparation of WO3-reduced graphene oxide nanocomposites with enhanced photocatalytic property. Ceramics Int., 41(2015), 5903-5908 10. J. Nawrocki, B. Kasprzyk-Hordern. The efficiency and mechanisms of catalytic ozonation. Appl. Catal. B: Environ., 99(2010), 27. 11. T. E. Agustina, H. M. Ang, V. K. Vareek, A review of synergistic effect of photocatalysis and ozonation on wastewater treatment. J. Photochem. Photobiol. C: Photochem. Rev., 6(2005),264. 12. B. K. Hordern, M. Ziolek, J. Nawrocki, Catalytic ozonation and methods of enhancing molecular ozone reactions in water treatment, Appl. Catal. B: Environ., 46(2003), 639. 13. M. Mehrjouei, S. Muller, D. Moller, Degradation of oxalic acid in a photocatalyticozonation system by means of Pilkington Active glass, J. Photochem. Photobiol. A: Chem., 217(2011), 417. 14. Y. Jing, L. Li, Q. Zhang, P. Lu, P. Liu, X. Lü, Photocatalyticozonation of dimethylphthalate with TiO2 prepared by a hydrothermal method, J. Hazard. Mater., 189(2011), 40-47. 15. F. J. Beltran, A. Aguinaco, J. F. García-Araya, Kinetic modelling of TOC removal in the photocatalyticozonation of diclofenac aqueous solutions, Appl. Catal. B: Environ., 100(2010), 289. 16. S. Nishimoto, T. Mano, Y. Kameshima, M. Miyake, Photocatalytic water treatment over WO3 under visible light irradiation combined with ozonation, Chem. Phys. Lett., 500(2010), 86. 17. T. Oyama, I. Yanagisawa, M. Takeuchi, T. Koike. Remediation of simulated aquatic sites contaminated with recalcitrant substrates by TiO2/ozonation under natural sunlight, Appl. Catal. B. Environ., 1(2009), 242. 18. R. Rajeswari, S. Kanmani, A study on synergistic effect of photocatalyticozonation for carbaryl degradation, Desalination., 242(2009), 277. 19. L. Zou, B. Zhu, The synergistic effect of ozonation and photocatalysis on color removal from reused water, J. Photochem. Photobiol. A. Chem., 196(2008), 24. 20. F. J. Beltran, A. Aguinaco, J. F. Garcıa-Araya, A. Oropesa, Ozone and photocatalytic processes to remove the antibiotic sulfamethoxazole from water, Water Res., 42(2008), 3799. 21. M. J. Farre, M. I. Franch, J. A. Ayllón, J.Peral, X. Domenech, Biodegradability of treated aqueous solutions of biorecalcitrant pesticides by means of photocatalyticozonation, Desalination., 211(2007), 22. 22. A. M. Amat, A. Arques, M. A. Miranda, S. Segui, R. F. Vercher, Degradation of rosolic acid by advanced oxidation processes: ozonation vs. solar photocatalysis, Desalination, 212(2007), 114. 23. J. S. Hur, S. O. Oh, K. M. Lim, J. S. Jung, J. W. Kim, Y. J. Koh, Novel effects of TiO2 photocatalytic ozonation on control of postharvest fungal spoilage of kiwifruit, Postharvest Biol. Technol., 35(2005), 109. 24. L. Li, W. Zhu, L. Chen, P. Zhang, Z. Chen, Photocatalyticozonation of dibutyl phthalate over TiO2 film. J. Photochem. Photobiol. A. Chem., 175(2005), 172. 25. M. Addamo, V. Augugliaro, E. G. Lopez, V. Loddo, G. Marci, L. Palmisano, Oxidation of oxalate ion in aqueous suspensions of TiO2 by photocatalysis and ozonation, Catal. Today., 107-108(2005), 612. 26. D. L. Pavia, G. M. Lampman, G. S. Kaiz, Introduction to Spectroscopy: A Guide for Students of Organic Chemistry, W. B. Saunders Company, 1987. 27. J. Wang, F. Ren, B. Jia, X. Liu, Solvothermal synthesis and characterization of NiFe2O4 nanospheres with adjustable sizes. Solid State Comm., 150(2010), 1141. 28. K. Tanaka, S. M. Robledo, T. Hisanaga, R. Ali, Z. Ramli, W. A. Bakar, Photocatalytic degradation of 3,4-xylyl N-methylcarbamate (MPMC) and other carbamate pesticides in aqueous TiO2 suspensions. J. Mol. Catal. A: Chem., 144(1999), 425. 29. I. K. Konstantinou, T. A. Albanis, TiO2-assisted photocatalytic degradation of azo dyes in aqueous solution: kinetic and mechanistic investigations-a review, Appl. Catal. B: Environ,. 49(2004), 1. 30. O. Gimeno, M. Carbajo, M. J. Lopez, J. A. Melero, F. J. Beltran, F. J. Rivas. Photocatalytic promoted oxidation of phenolic mixtures: an insight into operating and mechanistic aspects. Water Res., 41(2007), 4672. 31. I. Arsalan-Alaton, A review of the effects of dye-assisting chemicals on advanced oxidation of reactive dyes in wastewater, Color. Technol., 119(2003), 345.

Article's file
Page view: 2967
Article's download quantity : 33

Article System Login

Prof. Zahra Ranjbar
Dr. Farahnaz Nourmohammadian
Assistant Editor:
Dr. Mozhgan Hosseinnezhad
ISSN (online):
Institute for Color Science and Technology (ICST)

Quick Access
What is your opinion about the manuscript subscription system of PCCC website?
Website Statistics
Page view:2,968
Online Visitors:31