Basic dyes Removal by Natural Salvadora Persica Adsorbent

Journal: Vol. 10, No.2, 2017 - Article 6   Pages :  115 Until 128

Article Code:

A. Hamidi: Shahrood of University Technology - Faculty of Mining, Petroleum and Geophysics Engineering
K. Seifpanahi-Shabani: Shahrood University of Technology - Faculty of Mining, Petroleum and Geophysics Engineering
M. Karamoozian: Shahrood of University Technology - Faculty of Mining, Petroleum and Geophysics Engineering

Article's abstract:

In this paper, the results of studies of the sorption activity of Salvadora Persica fine particles that were provided from internal natural resources at Iran, with respect to Crystal Violet, Basic Violet-16 and Basic Blue-41 dyes were presented. Thus, Salvadora Persica particles were modified and prepared via particle size decreasing and characterized by CHNS, XRD, SEM and FT-IR analysis. In the batch system the influence of pH, adsorbent dosages and dye initial concentration was investigated. The results of isotherm and kinetics studies show that the Langmuir isotherm and pseudo-second order kinetic have better correlation with the experimental data. Calculations of thermodynamic parameters show negative Gibbs free energy ∆G values or spontaneous reaction, the enthalpy ∆H changes shows the exothermic process and values of entropy ∆S indicate low randomness at the solid/solution interface during the uptake of dyes. So, these locally available cheap adsorbent for the removal of basic dyes from the aqueous solution has high efficiency, also can be utilized for other water pollutants such as toxic elements.

Salvadora Persica, Basic dyes, Adsorption, Wastewater treatment.

1. Nouren Sh, Nawaz Bhatti H. Mechanistic study of degradation of basic violet 3 by Citrus limon peroxidase and phytotoxicity assessment of its degradation products. Biochemical Engineering Journal 2015; 95: 9-19. 2. Ghaedi M, Ansari A, Habibi M, Asghari A. Removal of malachite green from aqueous solution by zinc oxide nanoparticle loaded on activated carbon: Kinetics and isotherm study. J.Eng. Chem 2014; 20:17-28. 3. Roosta M, Ghaedi M, Daneshfar A, Daneshfarin S, Sahraei R, Purkait M. Simultaneous ultrasound-assisted removal of sunset yellow and erythrosine by Zns:Ni nanoparticles loaded on activated carbon: Optimization by central composite design. Ultrason Sonochem 2014; 21: 1441-1450. 4. Roosta M, Ghaedi M, Daneshfar A, Sahraei R, Asghari A. Optimization of the ultrasonic assisted removal of methylene blue by gold nanoparticles loaded on activated carbon using experimental design methodology. Ultrason Sonochem. 2014; 21(1):242-52. 5. Arunarani A, Chandran P, Ranganathan B., Vasanthi N, Sudheer K. Bioremoval of Basic Violet 3 and Acid Blue 93 by Pseudomonas putida and its adsorption isotherms and kinetics. Colloids and Surfaces B: Biointerfaces 2013; 102: 379-384. 6. Alpat K, Ozbayrak O, Alpat S, Akcay H. The adsorption kinetics and removal of cationic dye, Toluidine Blue O, from aqueous solution with Turkish zeolite. J. Hazard. Mater 2008; 151: 213-220. 7. Shuai A, Xuevan L, Lijun Y, Lei Z. Enhancement removal of crystal violet dye using magnetic calcium ferrite nanoparticle: Study in single- and binary-solute systems. Chemical Engineering Research and Design 2015; 94: 726–735. 8. Saha D, Chakraborty S, Chowdhury S. Batch and continuous (fixed-bed column) biosorption of crystal violet by Artocarpus heterophyllus (jackfruit) leaf powder. Colloied and Surfaces B: Biointerfaces 2012; 92: 262-270. 9. Khan A T, Khan A E, Shahjahan. Removal of basic dyes from aqueous solution by adsorption onto binary iron-manganese oxide coated kaolinite: Non-linear isotherm and kinetics modeling. Applied Clay Science 2015; 107: 70–77. 10. Maria R, Alexandros A, Vassiliadis. Interactions between C.I. Basic Blue 41 and aluminosilicate sorbents. Journal of Colloid and Interface Science 2005; 291: 37–44. 11. Sumanjit, Seema R, Mahajan R. Equilibrium, kinetics and thermodynamic parameters for adsorptive removal of dye Basic Blue 9 by ground nut shells and Eichhornia. Arabian Journal of Chemistry 2012; article in press. 12. Chowhury S, Mishra R, Saha P, Kushwaha P. Adsorption thermodynamics, kinetics and isotermic heat of adsorption of malachite green onto chemically modified rice husk. Desalination 2011; 265: 159-168. 13. Schoonen M, Schoonen J. Removal of crystal violet from aqueous solutions using coal. J. Colloid Interface Sci 2014; 422: 1-8. 14. Alkan M, Dogan M, Turhan Y, Demirbas O, Turan P. Adsorption kinetics and mechanism of maxilon blue 5G dye on sepiolite from aqueous solutions. Chem. Eng. J. 2008; 139: 213-223. 15. Kan T, Jiang X, Zhou L, Yang M, Duan M, Liu P and Jiang X. Removal of methyl orang from aqueous solutions using a bentonite modified with a new Gemini surfactant. Appl. Clay Sci 2011; 54: 184-187. 16. Ahmad M, Alrozi R. Removal of malachite green dye from aqueous solution using rambutan peel-based activated carbon: equilibrium, kinetic and thermodynamic studies. Chem. Eng. J. 2011; 171: 510-516. 17. Saeed A, Sharif M, Lqbal M. Application potential of grapefruit peel as dye sorbent: Kinetics, equilibrium and mechanism of crystal violet adsorption. Hazardous Materials 2010; 179: 564-572. 18. Jain S, Jayaram R. Removal of basic dyes from aqueous solution by low-cost adsorbent: Wood apple shell. Desalination 2010; 250: 921-927. 19. Almas K. The effects of extracts of chewing sticks (Salvadora Persica) on healthy and periodontally involved human dentine. A SEM study. Indian J Dent Res 2001; 12: 127-132. 20. Hanan B, Basma G, Al-Sulaiman H. The efficacy of Salvadora persica extract in the elimination of the intracanal smear layer: A SEM study. The Saudi Dental 2012; 24: 71-77. 21. Ramoliy P, Patel H, Pandey A. Effect of salinization of soil on growth and macro- and micro-nutrient accumulation in seedlings of Salvadora persica (Savadoraceae). Forest Ecology and Management 2004; 202: 181-193. 22. Khatak M, Khatak S, Siddqui A, Vasudeya N, Aggarwal P. Salvadora persica, Pharmacogn Rev. Jul- Dec 2010; 4: 209-214. 23. Halawany S, A review on miswak (Salvadora persica) and its effect on various aspects of oral health. The Saudi Dental 2012; 24: 63-69. 24. Sanogo R, Monforte M, Daquino A, Rossitto A, Mauro D, Galati E. Antiulcer activity of Salvadora persica structural modification. Ohytomedicine 1999; 6: 363-366. 25. Wahid F, Mohammadzai I U, Khan A, Shah Z, Hassan W, Ali N. Removal of toxic metals with activated carbon prepared from Salvadora Persica. Arabian Journal of Chemistry 2013; article in press. 26. Moawed, E.A., Abulkibash, A.B. Selective separation of Light green and Safranin O from aqueous solution using Salvadora persica (Miswak) powder as a new biosorbent. Journal of Saudi Chemical Society 2012; article in press. 27. Mansoureh Z, Alireza B. Highly efficient removal of basic blue 41 with nanoporous silica. Water Resources and Industry 2014; 5: 49–57. 28. Chahrazed D, Rachida Z, Faycal D, Bachir B, Abdelaziz L, Ali M, Marek R. Adsorption of dyes on activated carbon prepared from apricot stones and commercial activated carbon. Journal of the Taiwan Institute of Chemical Engineers 2015; 000: 1–10. 29. Yinhua J, Yingying L, Fumei Z, Leiqun G, Liang Ni. Equilibrium and kinetic studies of C.I. Basic Blue 41 adsorption onto N, F-codoped flower-like TiO2 microspheres. Applied Surface Science 2013; 273: 448– 456. 30. Khormaei M, Nasernejad B, Edrisi M, Eslamzadeh T. Copper biosorption from aqueous solutions by sour orange residue. Journal of Hazardous Materials 2007; 149(2,): 269–274. 31. Seifpanahi-Shabani K, Doulati-Ardejani F, Badii K, Olya M. Preparation and characterization of novel nano-mineral for the removal of several heavy metals from aqueous solution: Batch and continuous systems. Arabian Journal of Chemistry 2013, article in press. 32. Mohammad T, Francesco A, Ada F, Giorgio R. Use of N-methylformanilide as swelling agent for meta-aramid fibers dyeing: Kinetics and equilibrium adsorption of Basic Blue 41. Dyes and Pigments 2015; 113: 554-561. 33. Najafi M, Yousefi Y, Rafati A. Synthesis, characterization and adsorption studies of several heavy metal ions on amino-functionalized silica nano hollow sphere and silica gel. Separation and Purification Technology 2012; 85: 193–205. 34. Khan T A, Khan E K, Shahjahan. Removal of basic dyes from aqueous solution by adsorption onto binary iron-manganese oxide coated kaolinite: Non-linear isotherm and kinetics modeling. Applied Clay Science 2015; 107: 70–77. 35. Pal U, Sandoval A, Uribe Madrid S I, Corro G, Sharma V, Mohanty P. Mixed titanium, silicon, and aluminum oxide nanostructures as novel adsorbent for removal of rhodamine 6G and methylene blue as cationic dyes from aqueous solution. Chemosphere 2016; 163: 70-77. 36. Anirudhan T, Ramachandr M. Adsorptive removal of basic dyes from aqueous solutions by surfactant modified bentonite clay (organoclay): Kinetic and competitive adsorptionisotherm. Process Safety and Environmental Protection 2015; 9 5: 215–225. 37. Christianah Olakitan Ijagbemi, Mi-Hwa Baek, Dong-Su Kim, Montmorillonite surface properties and sorption characteristics for heavy metal removal from aqueous solutions, Journal of Hazardous Materials 2009, 166, 538–546. 38. Koolia K, Yan L, Al-Fazea R, Al-Sehimia A. Removal enhancement of basic blue 41 by brick waste from an aqueous solution. Arabian Journal of Chemistry 2015; 8(3): 333–342 39. Yonghui L, Xingbing H, Guomin H, Qijian T, Wenyong H. Removal of Crystal Violet from aqueous solution using powdered mycelial biomass of Ceriporia lacerata P2. Journal of Environmental Sciences 2011; 23: 2055–2062. 40. Arunagiri A, Indulekha J, Kalaichelvi P, Anantharaj R. Removal of crystal violet dye from aqueous solution using triton X-114 surfactant via cloud point extraction. Engineering Science and Technology, an International Journal 2014; 17: 137-144. 41. Monika W, Małgorzata W, Vladimir M, Vladimir Z. Adsorptive removal of acid, reactive and direct dyes from aqueous solutions and wastewater using mixed silica–alumina oxide. Powder Technology 2015; 278: 306–315.

Article's file
Page view: 557
Article's download quantity : 13

Article System Login

Prof. Zahra Ranjbar
Dr. Farahnaz Nourmohammadian
Assistant Editor:
Dr. Mozhgan Hosseinnezhad
ISSN (online):
Institute for Color Science and Technology (ICST)

Quick Access
What is your opinion about the manuscript subscription system of PCCC website?
Website Statistics
Page view:558
Online Visitors:70