Evaluating the Role of antioxidants in the stabilization of hydroxypropyl cellulose by ATR-FTIR Spectroscopy

Journal: Vol.11, No.2, Spring 2018 - Article 4   Pages :  93 Until 101

Article Code:

H. Ahmadi: Art University of Isfahan - Department of Conservation of Cultural and Historic Objects
S. Mallakpour: Isfahan University of Technology - Organic Polymer Chemistry Research Laboratory, Department of Chemistry,Research Institute for Nanotechnology and Advanced Materi
A. Koochakzaei: Art University of Isfahan - Department of Conservation of Cultural and Historic Objects

Article's abstract:

This study is aimed at evaluating the performance of tetrakismethylene-3-3,5-di-tert-butyl-4-hydroxyphenyl propionate methane S1010, tris2,4-di-tert-butylphenyl phosphite S1680 and ascorbic acid AA antioxidants in stabilization of hydroxypropyl cellulose HPC. For this purpose, a number of films with weight percent ratios of 0.4 w/w were prepared in a 1 isopropanol solution w/v. Then, the films underwent accelerated aging processes at the 3 light UV; 216hr, dry-heat 120°C; 240 hr and moist-heat 70°C; RH: 95; 240 hr conditions. During the aging processes, structural changes were studied using the attenuated total reflectance Fourier transform infrared ATR-FTIR spectroscopy and based on the defined destruction indices. In addition, changes in color of films were evaluated by colorimetry in CIELab system before and after the aging process. According to the obtained results, the S1010 phenolic antioxidant led to improvements in color and structure stabilization of HPC against environmental destructing factors in all three destruction processes of photooxidation, thermooxidation and hydrothermal.

Polymer degradation, Hydroxypropyl cellulose (HPC), Oxidation, Antioxidant, ATR-FTIR

1. S. D. Mansfield, R. Meder, Cellulose hydrolysis – the role of monocomponent cellulases in crystalline cellulose degradation, Cellulose, 10(2003), 159-169. 2. Y. Guo, P. Wu, Investigation of the hydrogen-bond structure of cellulose diacetate by two-dimensional infrared correlation spectroscopy, Carbohydr. Polym., 74(2008), 509-513. 3. S. Kalia, B. S. Kaith, I. Kaur (Eds.), Cellulose Fibers: Bio- and Nano-Polymer Composites, Springer, Berlin, 2011, 43-60. 4. C. Clasen, W. M. Kulicke, Determination of viscoelastic and rheo-optical material functions of water-soluble cellulose derivatives, Prog. Polym. Sci., 26(2001), 1839-1919. 5. M. Bagheri, S. Shateri, Synthesis and characterization of novel liquid crystalline cholesteryl-modified hydroxypropyl cellulose derivatives, J. Polym. Res., 19(2012), 9842. 6. Y. S. Yang, Y. Zhou, F. B. Yin Chiang, Y. Long, Temperature-responsive hydroxypropylcellulose based thermochromic material and its smart window application, RSC Adv., 6(2016), 61449-61453. 7. K. Sudarsan Reddy, M. N. Prabhakar, P. Kumara Babu, G. Venkatesulu, U. Sajan Kumarji Rao, K. Chowdoji Rao, M. C. S. Subha, Miscibility Studies of Hydroxypropyl Cellulose/Poly(Ethylene Glycol) in Dilute Solutions and Solid State, Int. J. Carbohydr. Chem., 2012(2012), 906389. 8. A. Abbas, M. A. Hussain, M. Amin, M. N. Tahir, I. Jantan, A. Hameed, S. N. A. Bukhari, Multiple cross-linked hydroxypropylcellulose-succinate-salicylate: prodrug design, characterization, stimuli responsive swelling-deswelling and sustained drug release, RSC Adv., 5(2015), 43440-43448. 9. J. Li, F. Wu, X. Lin, L. Shen, Y. Wang, Y. Feng, Novel application of hydroxypropyl methylcellulose to improving direct compaction properties of tablet fillers by co-spray drying, RSC Adv., 5(2015), 69289-69298. 10. C. D. Nechifor, A. I. Barzic, I. Stoica, V. Cloşca, D. O. Dorohoi, Study on glucose release ability from hydroxypropyl cellulose films, Polym. Bull., 72(2015), 549-563. 11. Z. Naeif Majeed, H. Hashim Mohammed, S. Ahmed Farhan, Study the Photodegradation of Hydroxypropyl Cellulose in Presence and Absence of Benzophenone and Eosine Dye, Chem. and Mater. Res., 6(2014), 18-25. 12. A. Immaneni, A. L. Kuba, A. J. McHugh, Effects of Temperature and Solvent on the Rheo-optical Behavior of Hydroxypropylcellulose Solutions, Macromolecules, 30(1997), 4613-4618. 13. T. Cai, Z. Hu, B. Ponder, J. St. John, D. Moro, Synthesis and Study of and Controlled Release from Nanoparticles and Their Networks Based on Functionalized Hydroxypropylcellulose, Macromolecules, 36(2003), 6559-6564. 14. V. V. Khutoryanskiy, M. G. Cascone, L. Lazzeri, N. Barbani, Z. S. Nurkeeva, G. A. Mun, A. V. Dubolazov, Morphological and thermal characterization of interpolymer complexes and blends based on poly(acrylic acid) and hydroxypropylcellulose, Polym. Int., 53(2004), 307-311. 15. K. Sudarsan Reddy, M. N. Prabhakar, K. Madhusudana Rao, D. M. Suhasini, V. Naga Maheswara Reddy, P. Kumara Babu, K. Sudhakar, A. Chandra Babu, M. C. S. Subha, K. Chowdoji Rao, Development and Characterization of Hydroxy Propyl Cellulose/Poly(vinyl alcohol) Blends and Their Physico-Chemical Studies, Indian J. Adv. Chem. Sci., 2(2013), 38-45. 16. R. L. Feller, M. Wilt, Evaluation of Cellulose Ethers for Conservation, Getty Conservation Institute, Los Angeles, 1993. 17. E. Yousif, R. Haddad, Photodegradation and photostabilization of polymers, especially polystyrene: review, SpringerPlus, 2(2013), 398-404. 18. K. Kavkler, A. Demsar, Application of FTIR and Raman Spectroscopy to Qualitative Analysis of Structural Changes in Cellulosic Fibres, Tekstilec, 55(2012), 19-31. 19. E. Yousif, A. Hasan, Photostabilization of poly(vinyl chloride) – Still on the run, J. Taibah Univ. Sci., 9(2015), 421-448. 20. T. Anjali, Modification of carboxymethyl cellulose through oxidation, Carbohydr. Polym., 87(2012), 457-460. 21. N. Herascu, M. Simileanu, R. Radvan, Color Changes in The Artwork Materials Aged by UV Radiation, Rom. Rep. Phys., 60(2008), 95-103. 22. L. M. Proniewicz, C. Paluszkiewicz, A. Wesełucha-Birczyńska, A. Barański, D. Dutka, FT-IR and FT-Raman study of hydrothermally degraded groundwood containing paper, J. Mol. Struct., 614(2002), 345-353. 23. N. A. El-Wakil, Y. Fahmy, R. E. Abou-Zeid, A. Dufresne, S. El-Sherbiny, Liquid crystalline behavior of hydroxypropyl cellulose esterified with 4-alkoxybenzoic acid, BioResources, 5(2010), 1834-1845. 24. K. A. Kristiansen, A. Potthast, B. E. Christensen, Periodate oxidation of polysaccharides for modification of chemical and physical properties, Carbohyd. Res., 345(2010), 1264-1271. 25. M. Rinaudo, Periodate Oxidation of Methylcellulose: Characterization and Properties of Oxidized Derivatives, Polymers, 2(2010), 505-521. 26. S. M. Salih (Ed.), Fourier Transform - Materials Analysis, InTech, Shanghai, 2012, 45-68. 27. C. Cao, Z. Yang, L. Han, X. Jiang, G. Ji, Study on in situ analysis of cellulose, hemicelluloses and lignin distribution linked to tissue structure of crop stalk internodal transverse section based on FTIR microspectroscopic imaging, Cellulose, 22(2015), 139-149. 28. Y. Huang, H. Kang, G. Li, C. Wang, Y. Huang, R. Liu, Synthesis and photosensitivity of azobenzene functionalized hydroxypropylcellulose, RSC Adv., 3(2013), 15909-15916. 29. J. Łojewska, P. Miśkowiec, T. Łojewski, L. M. Proniewicz, Cellulose oxidative and hydrolytic degradation: In situ FTIR approach, Polym. Degrad. Stabil., 88(2005), 512-520. 30. N. Abidi, L. Cabrales, E. Hequet, Fourier transform infrared spectroscopic approach to the study of the secondary cell wall development in cotton fiber, Cellulose, 17(2010), 309-320. 31. T. Łojewski, P. Miśkowiec, M. Missori, A. Lubańska, L. M. Proniewicz, J. Łojewska, FTIR and UV/vis as methods for evaluation of oxidative degradation of model paper: DFT approach for carbonyl vibrations, Carbohydr. Polym., 82(2010), 370-375. 32. A. Barik, T. Patnaik, P. Parhi, S. K. Swain, R. K. Dey, Synthesis and characterization of new shellac–hydroxypropylmethylcellulose composite for pharmaceutical applications, Polym. Bull., 74(2017), 3467-3485. 33. R. Johnston-Feller, Color Science In The Examination Of Museum Objects: Nondestructive Procedures, Getty Conservation Institute, Los Angeles, 2001

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